Modern Binders for Solid Propellants: Mechanical and Technological Aspects of Performance Formation
DOI:
https://doi.org/10.20535/2521-1943.2026.10.1(108).347016Keywords:
solid rocket propellant, binder, thermoplastic elastomer, thermosetting polymer, additive manufacturing, 3D printing, recycling, specific impulse, thermodynamic modelingAbstract
Background. Modern solid propellants are widely used in various propulsion systems, where their performance is determined not only by energetic characteristics but also by the properties of binder systems that ensure structural integrity and stability of the propellant grain.
Objective. The aim of this study is to analyze modern binders for solid propellants and to develop an approach to selecting effective compositions based on both physicochemical and mechanical characteristics.
Methods. The study is based on the analysis and generalization of current binder systems used in solid propellants, including thermosetting and thermoplastic binders, with consideration of their influence on mechanical behavior, structural integrity, and operational performance.
Results. It is shown that binder properties significantly affect not only the energetic performance but also the mechanical strength, deformation resistance, and reliability of propellant grains under operational conditions. An integrated approach to the selection of binder systems is proposed, which combines energy-based and mechanical criteria.
Conclusions. The proposed approach allows for a more comprehensive evaluation of solid propellant efficiency and can be used in the design and development of advanced propulsion systems with improved performance and reliability.
References
- D. G. Baird and D. I. Collias, Polymer processing: Principles and design, 2nd ed., Wiley, 2014. [Online]. Available: https://www.perlego.com/book/2773416/polymer-processing-principles-and-design-pdf.
- A. Davenas, Solid rocket propulsion technology, Pergamon Press, 2012. [Online]. Available: https://aigaforum.com/documents/Solid_Rocket_Propulsion_Technology.pdf.
- M. D. Dickey, “Emerging applications of liquid metals featuring surface oxides,” ACS Applied Materials & Interfaces, Vol. 6(21), pp. 18369–18379, 2014, doi: https://doi.org/10.1021/am5043017.
- O. Dobrodomov, V. Proroka and O. Kulyk, “UAV launch methods,” Chall. issue mod. sci., Vol. 2, pp. 25–34, Jun. 2024, Accessed: May 07, 2026. [Online]. Available: https://cims.fti.dp.ua/j/article/view/153.
- Firehawk Aerospace. Firehawk Aerospace achieves U.S. Army milestone with successful flight tests of Javelin and Stinger-class solid rocket motors. Defense & Munitions. Accessed: Oct. 25, 2024. [Online]. Available: https://www.defenseandmunitions.com/news/firehawk-aerospace-achieves-us-army-milestone-with-successful-flight-tests-of-javelin-and-stinger-class-solid-rocket-motors/.
- Firehawk Aerospace awarded AFWERX contract. Airforce Technology, Accessed: Oct. 25, 2024. [Online]. Available: https://www.airforce-technology.com/news/firehawk-usaf-rocket-motors/.
- I. Gibson et al., Additive manufacturing technologies, 3rd ed., Springer, 2021. [Online]. Available: https://link.springer.com/book/10.1007/978-3-030-56127-7.
- C. Ingabire, D. Liang and L. Li, “Progress on additive manufacturing technology of solid propellants,” Energetic Materials Frontiers, Advance online publication, Vol. 6(2), pp. 224–263, 2025, doi: https://doi.org/10.1016/j.enmf.2025.06.001.
- Sh. Ismael et al., “Ammonium perchlorate catalyzed with novel porous Mn doped Co3O4 microspheres: superior catalytic activi-ty, advanced decomposition kinetics and mechanisms,” Journal of Thermal Analysis and Calorimetry, Vol. 148, pp. 11811–11824, 2023, doi: https://doi.org/10.1007/s10973-023-12456-y.
- F. L. Jin et al., “Synthesis and application of epoxy resins: A review,” Journal of Industrial and Engineering Chemistry, Vol. 29, pp. 1–11, 2015, doi: https://doi.org/10.1016/j.jiec.2015.03.026.
- B. I. Kaidymov and V. S. Gavazova, “Influence of the polymorphic transition of AP on the catalytic effect exerted by some homogeneous and heterogeneous additives on its thermal decomposition,” Sibran, 25 May, 2024.
- N. Kubota, Propellants and Explosives: Thermochemical Aspects of Combustion, Wiley-VCH, 2015, doi: https://doi.org/10.1002/9783527693481.
- N. Kumar et al., “The effect of process parameters on tensile behavior of 3D printed flexible parts of ethylene vinyl acetate (EVA),” Journal of Manufacturing Processes, Vol. 35, pp. 317–326, 2018, doi: https://doi.org/10.1016/j.jmapro.2018.08.013.
- F. Lee et al., “Hydroxyl-terminated polybutadienes (HTPB) and glycidyl azide polymer (GAP) as solid rocket propellant binders: A review of synthesis and properties,” European Polymer Journal, Vol. 238, 114209, 2025, doi: https://doi.org/10.1016/j.eurpolymj.2025.114209.
- V. K. Medvedev et al., “Unmanned aerial vehicles and their impact on the course of the Russian-Ukrainian war”, Science & Defence, Vol. 22, No. 2, pp. 52–59, 2023, doi: https://doi.org/10.33099/2618-1614-2023-22-2-52-59.
- NASA. Shuttle solid rocket booster (SRB) systems. Retrieved: Oct. 25, 2025.
- B. Tan et al., “3D Printing for Explosives and Propellants Applications,” Vol. 3(1), 200151, Additive Manufacturing Frontiers, 2024, doi: https://doi.org/10.1016/j.amf.2024.200151.
- PROPEP (Propellant Evaluation Program). (n.d.). *Serge77 – My Rocket Workshop*. Accessed: Oct. 25, 2025. [Online]. Available: https://serge77-rocketry.net/propep/propep.htm.
- A. Slonov et al., “Investigation of the properties of polyethylene and ethylene-vinyl acetate copolymer blends for 3D printing applications,” Polymers, Vol.15(20), 4129, 2023, doi: https://doi.org/10.3390/polym15204129.
- S. Song, “A study on ultra-low-pressure ratio technology on the basis of 3D-printed propellant for a solid rocket motor”, Aero-space, Vol. 10(10), 862, 2023, doi: https://doi.org/10.3390/aerospace10100862.
- J. P. Agrawal, High energy materials: Propellants, explosives and pyrotechnics, Wiley‐VCH Verlag GmbH & Co. KGaA, 2010, doi: https://doi.org/10.1002/9783527628803.
- United States Patent and Trademark Office. (2002). Urea hydrochloride stabilized solvent for cleaning stainless steel and alumi-num (U.S. Patent No. US6340660B1). [Online]. Available: https://patents.google.com/patent/US6340660B1/en.
- I. Yilgor and E. Yilgor, “Structure‐Morphology‐Property Behavior of Segmented Thermoplastic Polyurethanes and Polyureas Prepared without Chain Extenders,” Polymer Reviews, Vol. 47(4), pp. 487–510, 2007, doi: https://doi.org/10.1080/15583720701638260.
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